Superhydrophobic Polypropylene Functionalized with Nanoparticles for Efficient Fast Static and Dynamic Separation of Spilled Oil from Water.

Frequent oil spills not only threaten the ecosystem, but they are also a waste of a valuable source of energy. There is an urgent need to develop materials that can readily remove spilled oil from water bodies and also have the capacity to collect it for energy applications. Herein, a superhydrophobic fiber of functionalized polypropylene is engineered with the help of palmitic acid interaction with incorporated copper oxide nanoparticles. The successful development of functionalized polypropylene is confirmed by Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and energy-dispersive X-ray spectroscopy. The scanning electron microscopy images reveal that the surface roughness of the polypropylene is enhanced after functionalization. The optimized functionalized polypropylene displays an ultrahydrophobic surface with a water contact angle of 162.42°. The functionalized polyprolyene displays good absorption capacity. It has the capacity to take 30 to 40 times its own weight in oils and nonpolar organic solvents, which makes it useful for small spills. With a flux of 11 204 Lm-2 h-1, functionalized polypropylene is as an ideal material for the dynamic separation of oil spills from water. It also has excellent selectivity towards oil, water rejection, and oil absorption capacity.

Pubmed ID: 31565391