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On page 1 showing 1 ~ 3 papers out of 3 papers

Tuning the Surface Plasmon Resonance of Gold Dumbbell Nanorods.

  • Puskar Chapagain‎ et al.
  • ACS omega‎
  • 2021‎

Gold has always fascinated humans, occupying an important functional and symbolic role in civilization. In earlier times, gold was predominantly used in jewelry; today, this noble metal's surface properties are taken advantage of in catalysis and plasmonics. In this article, the plasmon resonance of gold dumbbell nanorods is investigated. This unusual morphology was obtained by a seed-mediated growth method. The concentration of chemical precursors such as cetyltrimethylammonium bromide and silver nitrate plays a significant role in controlling the shape of the nanorods. Indeed, the aspect ratio of dumbbell nanostructures was varied from 2.6 to 4. UV-visible absorption spectra revealed a shift of the longitudinal surface plasmon resonance peak from 669 to 789 nm. Having the plasmon resonance in the near infrared region helps to use those nanostructures as photothermal agents.


Influence of CdS Morphology on the Efficiency of Dye-Sensitized Solar Cells.

  • Entidhar Alkuam‎ et al.
  • ACS omega‎
  • 2018‎

Cadmium sulfide (CdS) used in dye-sensitized solar cells (DSSCs) is currently mainly synthesized by chemical bath deposition, vacuum evaporation, spray deposition, chemical vapor deposition, electrochemical deposition, sol-gel, solvothermal, radio frequency sputtering, and hydrothermal process. In this paper, CdS was synthesized by hydrothermal process and used with a mixture of titanium dioxide anatase and rutile (TiO2(A+R)) to build the photoanode, whereas the counter electrode was made of nanocomposites of conductive polymer polyaniline (PANI) and multiwalled carbon nanotubes (MWCNTs) deposited on a fluorine-doped tin oxide substrate. Two morphologies of CdS have been obtained by using hydrothermal process: branched nanorods (CdSBR) and straight nanorods (CdSNR). The present work indicates that controlling the morphology of CdS is crucial to enhance the efficiency of DSSCs device. Indeed, the higher power conversion energy of 1.71% was achieved for a cell CdSBR-TiO2(A+R)/PANI-MWCNTs under 100 mW/cm2, whereas the power conversion energy of 0.97 and 0.83% for CdSNR-TiO2(A+R)/PANI-MWCNTs and TiO2(A+R)/PANI-MWCNTs, respectively. Therefore, by increasing the surface to volume ratio of CdS nanostructures and the crystallite size into those structures opens the way to low-cost chemical production of solar cells.


Naked Selenium Nanoparticles for Antibacterial and Anticancer Treatments.

  • Luke D Geoffrion‎ et al.
  • ACS omega‎
  • 2020‎

Currently, antibiotic resistance and cancer are two of the most important public health problems killing more than ∼1.5 million people annually, showing that antibiotics and current chemotherapeutics are not as effective as they were in the past. Nanotechnology is presented here as a potential solution. However, current protocols for the traditional physicochemical synthesis of nanomaterials are not free of environmental and social drawbacks, often involving the use of toxic catalysts. This article shows the production of pure naked selenium nanoparticles (SeNPs) by a novel green process called pulsed laser ablation in liquids (PLAL). After the first set of irradiations, another set was performed to reduce the size below 100 nm, which resulted in a colloidal solution of spherical SeNPs with two main populations having sizes around ∼80 and ∼10 nm. The particles after the second set of irradiations also showed higher colloidal stability. SeNPs showed a dose-dependent antibacterial effect toward both standard and antibiotic-resistant phenotypes of Gram-negative and Gram-positive bacteria at a range of concentrations between 0.05 and 25 ppm. Besides, the SeNPs showed a low cytotoxic effect when cultured with human dermal fibroblasts cells at a range of concentrations up to 1 ppm while showing an anticancer effect toward human melanoma and glioblastoma cells at the same concentration range. This article therefore introduces the possibility of using totally naked SeNPs synthesized by a new PLAL protocol as a novel and efficient nanoparticle fabrication process for biomedical applications.


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